A Novel Heterostructure of BiOI Nanosheets Anchored onto MWCNTs with Excellent Visible-Light Photocatalytic Activity
نویسندگان
چکیده
Developing efficient visible-light-driven (VLD) photocatalysts for environmental decontamination has drawn significant attention in recent years. Herein, we have reported a novel heterostructure of multiwalled carbon nanotubes (MWCNTs) coated with BiOI nanosheets as an efficient VLD photocatalyst, which was prepared via a simple solvothermal method. The morphology and structure were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectroscopy (DRS), and specific surface area measurements. The results showed that BiOI nanosheets were well deposited on MWCNTs. The MWCNTs/BiOI composites exhibited remarkably enhanced photocatalytic activity for the degradation of rhodamine B (RhB), methyl orange (MO), and para-chlorophenol (4-CP) under visible-light, compared with pure BiOI. When the MWCNTs content is 3 wt %, the MWCNTs/BiOI composite (3%M-Bi) achieves the highest activity, which is even higher than that of a mechanical mixture (3 wt % MWCNTs + 97 wt % BiOI). The superior photocatalytic activity is predominantly due to the strong coupling interface between MWCNTs and BiOI, which significantly promotes the efficient electron-hole separation. The photo-induced holes (h⁺) and superoxide radicals (O₂-) mainly contribute to the photocatalytic degradation of RhB over 3%M-Bi. Therefore, the MWCNTs/BiOI composite is expected to be an efficient VLD photocatalyst for environmental purification.
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Figure S1. Time‐dependent UV‐vis absorbance spectra of the MO solution in the presence (a) TiO2; (b) BiOI/TiO2‐C10; (c) BiOI/TiO2‐C20; (d) BiOI/TiO2‐C30; (e) mechanical mixture of BiOI and TiO2 (M‐BT) under UV light irradiation; (f) EDX of BiOI/TiO2‐C30 (Bi:Ti = 0.4:1).
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